An update:
I replaced the discs and pads, they sounded fine when I took the car around the block all good. Today I've drove out and after a while of more braking, I've noticed the grinding came back, back left from the sounds of it and lucky I was just about back home but it sounded harsher this time.
The back left was also the caliper which was an absolute bugger to wind back in. Potentially seized caliper then?